Abstract
IN a recent investigation of the ionisation processes in methane, Hogness and Kvalnes (Phys. Rev., 32, December 1928), using a mass-spectrograph method, find that at 14.5 volts only CH4+ ions are formed, but at 15.5 volts two processes occur; either stable CH4+ ions are formed or unstable CH4+ ions which dissociate spontaneously into CH3+ ions and neutral hydrogen atoms, the probabilities of the processes occurring being approximately equal over a wide range of pressure.
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BRINDLEY, G. The Structure of the CH4 Molecule. Nature 123, 760–761 (1929). https://doi.org/10.1038/123760b0
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DOI: https://doi.org/10.1038/123760b0