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Ionization Energy of Li+ and He

Abstract

As a disagreement was found by Robinson1 between measured and calculated values for the ionization potential of Li+, I have made a direct calculation by the method described by Hylleraas2. The ionization potential in the 13th approximation is found to be 610,058 cm.-1. This result is in good agreement with the value 610,054 cm.-1 obtained from the Hylleraas' extrapolation formula for Z = 3.

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References

  1. Robinson, Phys. Rev., 51, 14 (1937).

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  2. Hylleraas, Z. Phys., 65, 209 (1930).

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  3. Bethe, “Handb. d. Physik”, vol. 24/I, p. 324, et seq.

  4. Edlén, Nova Acta Reg. Soc. Sci. Ups., (7) 9, No. 6, and Robinson, Phys. Rev., 51, 14 (1937).

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ERIKSSON, H. Ionization Energy of Li+ and He. Nature 140, 151 (1937). https://doi.org/10.1038/140151a0

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