Abstract
THE heterogeneous equilibria between hydrogen and the metallic chlorides have been extensively studied, notably by Berger and Crut1 using a static method, and by Jellinek and his collaborators2 using a dynamic method. More recently, Kapustinsky3 has studied the reduction of cuprous chloride with both hydrogen and deuterium, using a static method. The agreement among the results of different authors is not very satisfactory and we are engaged in further investigations of heterogeneous equilibria involving hydrogen and deuterium.
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References
Berger and Crut, C. R., 173, 977 (1921).
Jellinek and Uloth, Z. phys. Chem., 119, 161 (1926); Jellinek and Rudat, Z. phys. chem., 143, 244 (1929).
Kapustinsky, J. Amer. Chem. Soc., 58, 460 (1936).
Urey and Rittenberg, J. Chem. Phys., 1, 142 (1933).
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PARTINGTON, J., TOWNDROW, R. Heterogeneous Equilibria with Deuterium. Nature 140, 156 (1937). https://doi.org/10.1038/140156a0
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DOI: https://doi.org/10.1038/140156a0