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Structure of Alginic Acid

Abstract

ALGINIC acid, the industrial importance of which is increasing, constitutes a large proportion of the dry weight of certain seaweeds. It is noteworthy among polysaccharides in that it appears to be built up entirely of d-mannuronic acid residues, although its resistance to hydrolysis is so great that no quantitative transformation to d-mannuronic acid has been achieved1. The results we have recently obtained from a study of the action of methyl alcoholic hydrogen chloride on the polysaccharide show that high yields of d-mannuronic acid are obtainable from alginic acid.

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References

  1. Nelson and Cretcher, J. Amer. Chem. Soc., 51, 1914 (1929); 54, 3409 (1932). Bird and Haas, Biochem. J., 25, 403 (1931). Schoeffel and Link, J. Biol. Chem., 100, 397 (1933).

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  2. Hudson and Maclay, J. Amer. Chem. Soc., 60, 2059 (1938).

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  3. Chemistry and Industry, 58, 363 (1939).

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HIRST, E., JONES, J. & JONES, W. Structure of Alginic Acid. Nature 143, 857 (1939). https://doi.org/10.1038/143857a0

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