Abstract
Fredenhagen and Krefft1 have shown that, when molten KF.HF is electrolysed using a graphite anode, the anode is not ‘wetted’ by the electrolyte. The same effect has been noted by other investigators as, for example, Cady2.
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References
Fredenhagen and Krefft, Z. Electrochem., 35, 670 (1929).
Cady, Rogers and Carlson, J. Ind. Eng. Chem., 34, 443 (1942).
Möller, Z. phys. Chem., 65, 226 (1908).
Frumkin and Kabanov, Z. phys. Chem., 165, 433 (1933).
Taylor, Trans. Electrochem. Soc., 67, 301 (1925).
Koehler, "Principles and Applications of Electrochemistry" (J. Wiley and Sons, 1944).
v. Wartenberg, Z. Electrochem., 32, 330 (1926).
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RUDGE, A., HOWELL, W. & HILL, H. Anode Phenomena in Molten Electrolytes. Nature 160, 504 (1947). https://doi.org/10.1038/160504a0
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DOI: https://doi.org/10.1038/160504a0