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A New Route to Dihydrophenanthrene
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  • Letter
  • Published: 02 April 1949

A New Route to Dihydrophenanthrene

  • D. MURIEL HALL1 &
  • E. E. TURNER1 

Nature volume 163, page 537 (1949)Cite this article

  • 525 Accesses

  • 5 Citations

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Abstract

WE are at present engaged in the investigation of the configurations of certain reduced aromatic systems, and have been surprised to find how relatively inaccessible is 9 : 10-dihydrophenanthrene (I). Quite apart from the appreciable difficulty of obtaining pure phenanthrene, the reduction of this hydrocarbon requires experimental procedure which is unattainable in many university laboratories. Burger and Mosettig1 effected the dihydrogenation by using a copper-chromium-barium oxide catalyst at 220°, with a hydrogen pressure of about 200 atmospheres over a period of about nine hours.

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References

  1. Burger, A., and Mosettig, E., J. Amer. Chem. Soc., 57, 2731 (1935): 18, 1857 (1936). Cf. Durland, J. R., and Adkins, H., ibid., 59, 135 (1937).

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  2. Wittig, G., and Pockels, U., Ber., 72, 884 (1939). Wittig, G., and Witt, H., Ber., 74, 1474 (1941).

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  3. Kenner, J., and Turner, E. G., J. Chem. Soc., 99, 2101 (1911).

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  4. Krizewsky, J., and Turner, E. E., J. Chem. Soc., 115, 559 (1919). Turner, E. E., J. and Proc. Roy. Soc. N.S. Wales, 54, 37 (1920).

    Article  CAS  Google Scholar 

  5. Finholt, A. E., Bond, A. C., jun., and Schlesinger, H. I., J. Amer. Chem. Soc., 69, 1199 (1947). Nystrom, R. F., and Brown, W. G., ibid., 69, 1197, 2548 (1947).

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Author information

Authors and Affiliations

  1. Department of Chemistry, Bedford College, University of London,

    D. MURIEL HALL & E. E. TURNER

Authors
  1. D. MURIEL HALL
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  2. E. E. TURNER
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HALL, D., TURNER, E. A New Route to Dihydrophenanthrene. Nature 163, 537 (1949). https://doi.org/10.1038/163537b0

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  • Issue date: 02 April 1949

  • DOI: https://doi.org/10.1038/163537b0

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