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Structure of Monoxides of some Transition Elements at Low Temperatures

Abstract

IT has been shown by one of us1 that, at ordinary temperatures, the structure of nickel oxide is slightly deformed from face-centred cubic symmetry. Later work2 proved that at − 180° C. an increase in the rhombohedral deformation occurs. On the other hand, it was found that the departure from cubic symmetry vanishes at a temperature of about 200° C.

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References

  1. Rooksby, H. P., Nature, 152, 304 (1943).

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  2. Rooksby, H. P., Acta Crystallographica, 1, 226 (1948).

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  3. Lonsdale, K., and Smith, H., J. Sci. Instr., 18, 133 (1941).

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TOMBS, N., ROOKSBY, H. Structure of Monoxides of some Transition Elements at Low Temperatures. Nature 165, 442–443 (1950). https://doi.org/10.1038/165442b0

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