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Olefinic Nature of Anacardic Acid from Indian Cashew-nut Shell Liquid

Abstract

ANACARDIC acid, the major component of the liquid extracted by solvent from cashew-nut shells1, was regarded as a homogeneous chemical entity containing in its aliphatic side-chain of fifteen carbon atoms two double bonds until recently, when it was shown by Izzo and Dawson2 to be in fact a mixture of olefinic components of which they identified the mono-olefin in the form of a crystalline glycol of the methylated anacardic acid. The present communication reports the complete separation of the mixture into its several components and the determination of their olefinic structure.

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References

  1. Staedeler, Ann., 63, 137 (1847).

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  2. Izzo, P. T., and Dawson, C. R., J. Org. Chem., 14, 1039 (1949).

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  3. Backer, H. J., and Haack, N. H., Rec. Trav. Chim., 60, 661 (1941).

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  4. Paul, V. J., M.Sc. thesis, University of Madras (1951).

  5. Symes, W. F., and Dawson, C. R., J. Amer. Chem. Soc., 75, 4952 (1953).

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PAUL, V., YEDDANAPALLI, L. Olefinic Nature of Anacardic Acid from Indian Cashew-nut Shell Liquid. Nature 174, 604 (1954). https://doi.org/10.1038/174604a0

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