Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Alkaline-Earth Borohydrides and their Applications in Organic Syntheses

Abstract

WE have pointed out that the alkaline-earth metal borohydrides discovered by us are very suitable for the reduction of ketones and aldehydes to the corresponding alcohols1. The present communication deals with the application of these borohydrides—particularly of Ca(BH4)2—for reduction of other functional groups.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Kollonitsch, J., Fuchs, O., and Gábor, V., Nature, 173, 125 (1954).

    Article  ADS  CAS  Google Scholar 

  2. Carrara, G., Pace, E., and Cristiani, G., J. Amer. Chem. Soc., 74, 4949 (1952).

    Article  CAS  Google Scholar 

  3. Baltazzi, E., and Robinson, R., Chem. and Indust., 22, 540 (1953).

    Google Scholar 

  4. Paul, R., and Joseph, N., Bull. Soc. Chim. France, 550 (1952). Chaikin S. W., and Brown, W. G., J. Amer. Chem. Soc., 71, 125 (1949).

    Google Scholar 

  5. Grassmann, W., Hörmann, H., and Endres, H., Chem. Ber., 86, 1477 (1953).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

KOLLONITSCH, J., FUCHS, O. & GÁBOR, V. Alkaline-Earth Borohydrides and their Applications in Organic Syntheses. Nature 175, 346 (1955). https://doi.org/10.1038/175346a0

Download citation

  • Issue date:

  • DOI: https://doi.org/10.1038/175346a0

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing