Abstract
IN 1952, Nunn1 put forward a structure for sterculic acid (I), whereas we have assigned to it structure (II)2; Dijkstra and Duin3 have, however, rejected structure (II) on grounds which we believe to be inconsistent with the known facts.
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References
Nunn, J. R., J. Chem. Soc., 313 (1952).
Verma, J. P., Nath, Bhola, and Aggarwal, J. S., Nature, 175, 84 (1955).
Dijkstra, G., and Duin, H. J., Nature, 176, 71 (1955).
Derfer, J. M., Pickett, E. E., and Boord, C. E., J. Amer. Chem. Soc., 71, 2482 (1949).
Volkenburgh, R. V., Greenlee, K. W., Derfer, J. M., and Boord, E. C., J. Amer. Chem. Soc., 71, 3595 (1949).
Verma, J. P., Das Gupta, S., Nath, Bhola, and Aggarwal, J. S., J. Ind. Chem. Soc. (in the press).
Gilman, H., “Organic Chemistry”, 1, 36 (Wiley, New York, 1939).
Noller, C. R., “Organic Chemistry”, 559 (Saunders, London, 1951).
Royals, E. E., “Organic Chemistry”, 213, 219 (Prentice-Hall, New York, 1954).
Goss, F. R., Ingold, C. K., and Thorpe, J. F., J. Chem. Soc., 123, 327 (1923).
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VERMA, J., NATH, B. & AGGARWAL, J. Structure of Sterculic Acid. Nature 176, 1082 (1955). https://doi.org/10.1038/1761082a0
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DOI: https://doi.org/10.1038/1761082a0
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