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Mass Spectrometry of Substances of Low Volatility

Abstract

A LARGE range of substances which, because of their thermal instability or involatility, are unsuitable for admission in the gaseous state through a heated-inlet system into the ionization chamber of a mass spectrometer are usually studied by means of devices for volatilizing them very near the ionizing beam1–6. As a variant of the technique described by Bradt and Mohler5, a Metropolitan-Vickers M.S.3 tube has been modified for the study of the effects of heat on coal and coal extracts in the temperature range 60–450° C.

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References

  1. Honig, R. E., J. Chem. Phys., 22, 1610 (1954).

    ADS  Google Scholar 

  2. Chupka, W. A., Inghram, M. G., and Porter, R. F., J. Chem. Phys., 24, 792 (1956).

    Article  ADS  CAS  Google Scholar 

  3. Palmer, G. H., AERE-CD/R-1572 (Atomic Energy Research Establishment, Harwell, 1957).

  4. Bradt, P., Dibeler, V. H., and Mohler, F. L., J. Res. Nat. Bur. Stand., 50, 201 (1953).

    Article  CAS  Google Scholar 

  5. Bradt, P., and Mohler, F. L., J. Res. Nat. Bur. Stand., 55, 323 (1955).

    Article  CAS  Google Scholar 

  6. de Mayo, P., and Reed, R. I., Chem. and Indust., 1481 (1956).

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HOLDEN, H., ROBB, J. Mass Spectrometry of Substances of Low Volatility. Nature 182, 340 (1958). https://doi.org/10.1038/182340a0

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