Abstract
THE well-documented hypsochromic and bathochromic shifts observed in the wave-length maxima of the transmittance spectra of many solutes can be explained in many cases on the basis of solute–solvent interactions in which the polarity of the solvent and/or solute is an important factor in determining the type and magnitude of the shift1,2.
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References
McRae, E. H., J. Phys. Chem., 61, 562 (1957).
Brooker, L. S., and Sprague, R. H., J. Amer. Chem. Soc., 63, 3214 (1941).
Zeitlin, H., and Goya, H., Nature, 183, 1041 (1959).
Goya, H., Waugh, J. L. T., and Zeitlin, H., J. Phys. Chem., 66, 1206 (1962).
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ZEITLIN, H., GOYA, H. & WAUGH, J. Reflectance Spectra of Some Mercury (II) Compounds on Active Adsorbents. Nature 198, 178–179 (1963). https://doi.org/10.1038/198178b0
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DOI: https://doi.org/10.1038/198178b0
