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Thermal Decomposition of Benzyl Xanthate

Abstract

THERMAL decomposition of esters has been examined extensively in recent years, and the primary decomposition mechanism has been shown to be a cis elimination1. The existence of secondary pyrolytic mechanisms has also been amply described by Hurd and Blunck2; however, only sparse information has been obtained on the nature of these mechanisms3,4. In an attempt to clarify these reaction pathways, a study of the decomposition of benzyl xanthate was initiated.

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References

  1. DePuy, C. H., and King, R. W., Chem. Revs., 60, 431 (1960).

    Article  CAS  Google Scholar 

  2. Hurd, C. D., and Blunck, F. H., J. Amer. Chem. Soc., 60, 2419 (1938).

    Article  CAS  Google Scholar 

  3. Jones, E., and Ritchie, P. D., J. Chem. Soc., 4141 (1960).

  4. Risinger, G. E., and Mach, E. E., Nature, 196, 1091 (1962).

    Article  ADS  CAS  Google Scholar 

  5. Nametkin, S., and Kursanov, D., J. prakt. Chem., 112, 164 (1926).

    Article  CAS  Google Scholar 

  6. Alexander, E. R., and Mudrak, A., J. Amer. Chem. Soc., 72, 1810 (1950).

    Article  CAS  Google Scholar 

  7. Laakso, P. V., Suomen Kemistilchti, 16 B, 19 (1953). [CA 40, 46875].

    Google Scholar 

  8. Fromm, E., and Achert, O., Ber., 36, 538 (1903).

    Article  Google Scholar 

  9. Baumann, O., and Fromm, E., Ber., 24, 1456 (1891).

    Google Scholar 

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RISINGER, G. Thermal Decomposition of Benzyl Xanthate. Nature 198, 382 (1963). https://doi.org/10.1038/198382a0

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