Abstract
THE radiation chemistry of liquid alkanes (for example, cyclohexane, n-hexane) has been investigated extensively1. In particular, it has been shown that the addition of small amounts of certain substances, such as iodine or carbon tetrachloride, causes large changes in product yields. This ‘protective’ effect has been the subject of much discussion since it has an important bearing on the nature of the radiation-produced primary species. ‘Energy transfer’, free radical processes2–5 and scavenging of electrons6,7 have all been proposed.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on SpringerLink
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Swallow, A. J., Radiation Chemistry of Organic Compounds (Pergamon Press, 1960).
Marion, J. P., and Burton, M., J. Phys. Chem., 56, 560 (1952).
Dewhurst, H. A., J. Phys. Chem., 63, 813 (1959).
Hardwick, T. J., J. Phys. Chem., 65, 101 (1961).
Lamborn, J., and Swallow, A. J., J. Phys. Chem., 65, 920 (1961).
Schuler, R. H., J. Phys. Chem., 61, 1472 (1957).
Forrestal, L. J., and Hamill, W. H., J. Amer. Chem. Soc., 83, 1535 (1961).
Dainton, F. S., and Peterson, D. B., Nature, 186, 878 (1960); Proc. Roy. Soc., A, 267, 443 (1962).
Czapski, G., and Jortner, J., Nature, 188, 50 (1960).
Scholes, G., Simic, M., and Weiss, J. J., Disc. Farad. Soc. 36, 214 (1963).
Scholes, G., and Simic, M., J. Phys. Chem. (in the press).
Gordon, S., Hart, E. J., Matheson, M. S., Rabani, J., and Thomas, J. K., Disc. Farad. Soc., 36, Paper No. 14 (1963); Gatlinburg Conference (1963).
Freeman, G. R., J. Chem. Phys., 38, 1022 (1963).
Allen, A. O., and Hummel, A., Disc. Farad. Soc., 36, 95 (1963).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
SCHOLES, G., SIMIC, M. Reactions of Electrons in the γ-Radiolysis of Liquid Alkanes. Nature 202, 895–896 (1964). https://doi.org/10.1038/202895a0
Issue date:
DOI: https://doi.org/10.1038/202895a0
This article is cited by
-
Pulsradiolyse
Die Naturwissenschaften (1968)
-
Role of O− in the Gas Phase Radiolysis of Alkane–Nitrous Oxide Mixtures
Nature (1967)
-
Effect of an Electron-scavenging Solute on the Radiolysis of Cyclohexane
Nature (1966)
-
Labelled Products from the Internal Radiolysis of Liquid Cyclohexane saturated with Tritium Gas
Nature (1966)
-
A Correlation between Electron Affinity and Protection in the Radiation Chemistry of Hydrocarbons
Nature (1966)