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Applications of Magnetic Circular Dichroism and Optical Rotatory Dispersion Measurements

Abstract

Recent progress in the fields of magnetic circular dichroism (MCD) and magneto-optical rotatory dispersion (MORD) is reviewed and these techniques are contrasted with those of natural circular dichroism and optical rotatory dispersion. Apart from the fact that MCD and MORD do not require optically active compounds (optical activity being induced by the magnetic field), these physical tools offer spectroscopic information which is different or impossible to obtain by other means.

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References

  1. Djerassi, C., Optical Rotatory Dispersion (McGraw-Hill, New York, 1960).

    Google Scholar 

  2. Crabbé, P., Optical Rotatory Dispersion and Circular Dichroism in Organic Chemistry (Holden-Day, San Francisco, 1965). Velluz, L., Legrand, M., and Grosjean, M., Optical Circular Dichroism (Academic Press, New York, 1965).

    Google Scholar 

  3. Lowry, T. M., Optical Rotatory Power (Longmans Green, London, 1935, reprinted by Dover, New York, 1964).

    Google Scholar 

  4. Buckingham, A. D., and Stephens, P. J., Ann. Rev. Phys. Chem., 17, 399 (1966).

    Article  ADS  CAS  Google Scholar 

  5. Schooley, D. A., Bunnenberg, E., and Djerassi, C., Proc. US Nat. Acad. Sci., 56, 1377 (1966).

    Article  ADS  CAS  Google Scholar 

  6. Briat, B., Schooley, D. A., Records, R., Bunnenberg, E., and Djerassi, C., J. Amer. Chem. Soc., 89, 6170 (1967).

    Article  CAS  Google Scholar 

  7. Briat, B., Schooley, D. A., Records, R., Bunnenberg, E., and Djerassi, C., J. Amer. Chem. Soc., 89, 7062 (1967).

    Article  CAS  Google Scholar 

  8. Schatz, P. N., McCaffery, A. J., Suetaka, W., Henning, G. N., Ritchie, A. B., and Stephens, P. J., J. Chem. Phys., 45, 722 (1966).

    Article  ADS  CAS  Google Scholar 

  9. McCaffery, A. J., Stephens, P. J., and Schatz, P. N., Inorg. Chem., 6, 1614 (1967).

    Article  CAS  Google Scholar 

  10. Shashoua, V. E., J. Amer. Chem. Soc., 87, 4044 (1965); Arch. Biochem. Biophys., 111, 550 (1965).

    Article  CAS  Google Scholar 

  11. Moscowitz, A., Proc. Roy. Soc., A, 297, 16 (1967).

    Article  ADS  CAS  Google Scholar 

  12. Briat, B., and Djerassi, C., Bull. Soc. Chim. France (in the press).

  13. Briat, B., Schooley, D. A., Records, R., Bunnenberg, B., Djerassi, C., and Vogel, E., J. Amer. Chem. Soc. (in the press).

  14. Inter al., Briat, B., Billardon, M., Badoz, J., and Loriers, J., Anal. Chim. Acta, 34, 465 (1966).

    Article  CAS  Google Scholar 

  15. Foss, J. G., and McCarville, M. E., J. Amer. Chem. Soc., 89, 30 (1967).

    Article  CAS  Google Scholar 

  16. Clerc, J. T., Wipf, H. K., and Simon, W., Helv. Chim. Acta, 50, 1794 (1967).

    Article  CAS  Google Scholar 

Download references

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BRIAT, B., DJERASSI, C. Applications of Magnetic Circular Dichroism and Optical Rotatory Dispersion Measurements. Nature 217, 918–922 (1968). https://doi.org/10.1038/217918a0

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