Abstract
Kurtz and Robinson1 have recently proposed a physical model of the electro-optic effect. On its basis they have derived expressions for the electro-optic coefficients of centrosymmetric and non-centrosymmetric crystals. They have also established a relationship between the linear and the quadratic electro-optic coefficients in ferroelectric materials in terms of spontaneous polarization. According to this model the linear electro-optic coefficient vanishes for centrosymmetric crystals. This conforms with the general concept. The purpose of this communication is to point out that a small linear electro-optic effect is also expected to occur in centrosymmetric crystals. Kurtz and Robinson's model1 is modified with respect to this point and a rough theoretical estimate for linear electro-optic coefficients of such crystals is obtained.
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References
Kurtz, S. K., and Robinson, F. N. H., Appl. Phys. Lett., 10, 62 (1967).
Adler, E., Phys. Rev., 134, A, 728 (1964).
Terhune, R. W., Maker, P. D., and Savage, C. M., Phys. Rev. Lett., 8, 404 (1962).
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BALI, L. Linear Electro-optic Effect and Centrosymmetric Crystals. Nature 220, 472–473 (1968). https://doi.org/10.1038/220472a0
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DOI: https://doi.org/10.1038/220472a0