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Linear Electro-optic Effect and Centrosymmetric Crystals

Abstract

Kurtz and Robinson1 have recently proposed a physical model of the electro-optic effect. On its basis they have derived expressions for the electro-optic coefficients of centrosymmetric and non-centrosymmetric crystals. They have also established a relationship between the linear and the quadratic electro-optic coefficients in ferroelectric materials in terms of spontaneous polarization. According to this model the linear electro-optic coefficient vanishes for centrosymmetric crystals. This conforms with the general concept. The purpose of this communication is to point out that a small linear electro-optic effect is also expected to occur in centrosymmetric crystals. Kurtz and Robinson's model1 is modified with respect to this point and a rough theoretical estimate for linear electro-optic coefficients of such crystals is obtained.

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References

  1. Kurtz, S. K., and Robinson, F. N. H., Appl. Phys. Lett., 10, 62 (1967).

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  2. Adler, E., Phys. Rev., 134, A, 728 (1964).

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  3. Terhune, R. W., Maker, P. D., and Savage, C. M., Phys. Rev. Lett., 8, 404 (1962).

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BALI, L. Linear Electro-optic Effect and Centrosymmetric Crystals. Nature 220, 472–473 (1968). https://doi.org/10.1038/220472a0

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