Abstract
WE present here new results that disprove a widely discussed, and seemingly successful, structural model for polywater1, which was derived using semi-empirical calculations, and obtained its utility by consistently correlating more than twenty experimental observations. Defeat of this model thus casts serious doubt on the existence of a new water allotrope. It is important to distinguish clearly between the essentially empirical interrelation of experiments achieved by the original model and the current attack on it, because it is obvious from ref. 1 that we have placed ourselves in the unusual and all too easy to discredit position of being authors both of the original model and of the new results against it.
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References
Allen, L. C., and Kollman, P. A., Science, 167, 1443 (1970).
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ALLEN, L., KOLLMAN, P. Theoretical Evidence Against the Existence of Polywater. Nature 233, 550–551 (1971). https://doi.org/10.1038/233550a0
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DOI: https://doi.org/10.1038/233550a0