Abstract
METHYL chloroform (111 trichloro ethane) was introduced into general use in 1955–60 in response to the need for a general solvent which was less toxic than those then in use. Its ubiquitous presence in the northern and southern hemispheres, first reported in 1974 (ref. 1), has since been confirmed2,3. The only significant sources of methyl chloroform are industrial releases from its use as a cleaning agent and solvent. A principal sink for its removal from the atmosphere seems to be the reaction with OH radicals. The rate of its release to the atmosphere is known with some accuracy, and consequently the measurements of its growth in the atmosphere could provide valuable information on the strength of the OH reaction sink, not only for methyl chloroform but also for other important atmospheric gases which undergo similar reactions. This communication reports measurements of the abundance of methyl chloroform made during 5 yr in the northern and southern tropospheres.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on SpringerLink
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Lovelock, J. E. Nature 252, 292 (1974),
Grimsrud, E. P. & Rasmussen, R. A. Atmosph. Env. 9, 1 (1975)
Cox, R. A., Derwent, R. G., Eggleton, A. E. & Lovelock, J. E. Atmos. Env. 10, 305 (1976).
Lovelock, J. E., Maggs, R. J. & Wade, R. J. Nature 241 (1973).
‘Halocarbons’: Effects of Stratospheric Ozone (National Academy of Sciences, Washington DC, 1976).
Watson, R. T., Machado, E. S., Conway, B., Wagner, S. & Davis, D. D. J. phys. Chem (in the press).
Levy, H. Adv. Photochem. 9, 369 (1974).
Crutzen, P. Tellus 26, 47 (1974).
Wofsy, S. C., McConnell, J. C. & McElroy, M. B. J. geophys. Res. 77, 4477 (1972).
Warneck, P. Planet. Space Sci. 23, 1507 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
LOVELOCK, J. Methyl chloroform in the troposphere as an indicator of OH radical abundance. Nature 267, 32 (1977). https://doi.org/10.1038/267032a0
Received:
Accepted:
Issue date:
DOI: https://doi.org/10.1038/267032a0
This article is cited by
-
Uncertain road to ozone recovery
Nature (1999)
-
A record of atmospheric halocarbons during the twentieth century from polar firn air
Nature (1999)
-
Methane, carbon monoxide and methylchloroform in the southern hemisphere
Journal of Atmospheric Chemistry (1986)
-
A laser optical method for the determination of tropospheric OH concentrations
Applied Physics B Photophysics and Laser Chemistry (1984)