Figure 5

(a) The initial discharge–charge voltage profile of the lithium-oxygen (Li-O2) battery with Ru particles functionalized graphene aerogel (Ru-GA) cathode and the corresponding differential electrochemical mass spectrometry (DEMS) result. (b) The schematic representation of the charging process: (I) only O2 gas evolves, which is attributed to the delithiation of Li2O2 to form LiO2-like species and subsequent bulk oxidation. (II) CO2 started to evolve, assigned to the decomposition of by-products and accompanied by the oxidation of Li2O2.