Calculations examining the behaviour of free electrons in water suggest that they do not occupy a cavity as previously thought but reside in regions of increased water density.
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References
Larsen, R. E., Glover, W. J. & Schwartz, B. J. Does the hydrated electron occupy a cavity? Science 329, 65–69 (2010).
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Armstrong, G. Defying cavity. Nature Chem (2010). https://doi.org/10.1038/nchem.797
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DOI: https://doi.org/10.1038/nchem.797