Figure 4: Metal-catalysed step-growth radical polymerization of the abcc monomer.
From: Sequence-regulated vinyl copolymers by metal-catalysed step-growth radical polymerization
(a) Polymerization scheme of 7 with CuCl/N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA). (b) Conversion of monomer (7) measured by SEC with a ultraviolet detector and C–Cl and C=C bonds measured by 1H NMR in metal-catalysed step-growth radical polymerization with CuCl/PMDETA in bulk at 60 °C; [7]0=bulk; [CuCl]0=200 mM; [PMDETA]0=800 mM. (c) SECs of the obtained polymers.
