Figure 4: GFA versus composition diagram for the pseudobinary (Pd1−xNix) 80P20 system.

Input data are taken from refs 25, 26, 27, 28, 29, 30, 31, 32. Solid blue square symbols are calculated GFA from experimental trg and m values31,32 using equation (2). The solid blue line is a fit to the calculated GFA values. Dotted red line is a parabolic fit to the calculated contribution from fragility. Red open circles are experimental GFA data from refs 25, 26, 27, 28, 29, 30. The reader is referred to the Supplementary Information for details. Error bars represent experimental uncertainty of 15% in the maximum casting diameter as discussed in text.