Figure 3: Perovskite photocathode performance during H2 photogeneration.

(a) Typical linear sweep voltammetry of the perovskite-based photocathode at a scan rate of 5 mV s−1. The arrow denotes the scan direction. (b) Chronoamperometric trace recorded at an applied potential of 0 V versus RHE. An aqueous buffer solution (0.1 M borate, pH 8.5), chopped solar light irradiation (AM 1.5 G, 100 mW cm−2, λ>400 nm) and an inert (N2) atmosphere at room temperature were used in both experiments.