Figure 1: Structure and the sign of carriers in Sr3−xSnO.
From: Superconductivity in the antiperovskite Dirac-metal oxide Sr3−xSnO

(a) Powder X-ray diffraction spectrum of a superconductive Sr3−xSnO batch-A sample. The spectrum was taken at room temperature on a lightly crushed sample with Kapton film and vacuum grease protecting it from air. Some impurity peaks can be seen marked with asterisks. The inset compares the perovskite SrSnO3 and antiperovskite Sr3SnO, emphasizing the change in oxidation states: Sr2+ corresponds to Sn4−, Sn4+ to O2−, and O2− to Sr2+. (b) Hall coefficient measured as a function of temperatures showing hole-like carriers for a batch-A sample.