Table 4 Rules to derive symmetry invariants.

From: Improper electric polarization in simple perovskite oxides with two magnetic sublattices

Order Param.

C 2 [100] pc

C 2 [010] pc

C 3 + [111] pc

C 2 [110] pc

1′

P x

P x

Px

P y

P y

Px

P x

P y

Py

P y

P z

P x

Py

P y

P z

Pz

Pz

P x

Pz

Pz

P z

η xy

ηxy

ηxy

η yz

η xy

η xy

η xy

η yz

η yz

ηyz

η xz

ηxz

η yz

η yz

η xz

ηxz

η xz

η xy

ηyz

η xz

η xz

ω Rx

ω Rx

ωRx

ω Ry

ωRy

ωRx

ω Rx

ω Ry

ωRy

ω Ry

ω Rz

ωRx

ωRy

ω Ry

ω Rz

ωRz

ωRz

ω Rx

ω Rz

ωRz

ω Rz

A Rx

A Rx

ARx

A Ry

A Ry

ARx

A Rx

A Ry

ARy

A Ry

A Rz

A Rx

ARy

A Ry

A Rz

ARz

ARz

A Rx

ARz

ARz

A Rz

G Gd

G Gd

G Gd

G Gd

G Gd

G Gd

GGd

G Fe

G Fe

G Fe

G Fe

GFe

GFe

GFe

  1. Transformation of the various order parameters discussed in the text under the action of the generators of the mm point group and time reversal symmetry (1′). We indicate the axis of the two-fold (C2) and three-fold (C3+) rotations; is the spatial inversion. To write these transformation rules, we assume that the symmetry operations are centred on an A site of the perovskite lattice (see discussion in main text). All labels and indicated directions refer to the pseudo-cubic (pc) setting.