Figure 6: Product vibrational branching ratio as a function of collision energy. | Nature Communications

Figure 6: Product vibrational branching ratio as a function of collision energy.

From: Dynamical importance of van der Waals saddle and excited potential surface in C(1D)+D2 complex-forming reaction

Figure 6

This is defined as the ratio between the integral cross-section (ICS(ν′=1)) and ICS(ν′=0) for the C(1D)+D2(ν=0, j=0)→CD(ν′)+D reaction. Accurate quantum dynamics (QD) results calculated on our and PESs are compared with the available crossed-beam experimental value25, along with our QD results calculated on the RKHS PES and the roughly estimated lower limit of the QD value on the RKHS () and BJHL () PESs. The corresponding contributions of our and PESs are also shown, respectively.

Back to article page