Table 1 Summary findings of defects and electrochemistry in δ-MnO2 electrodes.

From: The critical role of point defects in improving the specific capacitance of δ-MnO2 nanosheets

Samples

AOS

[Mn3+] (%)

[Mn4+] (%)

[VMn] (%)

S.S.A. (m2 g1)

Cp (F g1)

R ct (Ω)

Na : Mn (fract.)

Reassembled MnO2 - pH 2

3.24

76

24

26.5

120

306

3

0.28

Reassembled MnO2 - pH 4

3.36

64

36

19.9

144

209

15

0.19

Protonated MnO2

3.59

41

59

18.3

4.5

103

23

0.09

  1. Comparison of defect structures and electrochemical supercapacitor properties of bulk protonated HxMnO2 and MnO2 nanosheet assemblies.