Table 1 Rate constants for NC using the kinetic model shown in Fig. 3.
From: Unified model for singlet fission within a non-conjugated covalent pentacene dimer
k1 (s−1) | k2 (s−1) | k−2 (s−1) | k3 (s−1) | |
|---|---|---|---|---|
295 K | 9.5±0.7 × 107 | 2.4±0.1 × 109 | 5.0±0.3 × 107 | 1.1±0.1 × 107 |
105 K | 5.1±0.2 × 107 | 3.3±0.9 × 108 | 1.0±0.1 × 106 | 6.7±0.1 × 106 |
k−3 (s−1) | k4 (s−1) | k5 (s−1) | k6 (s−1) | |
295 K | 4.8±0.1 × 106 | 1.0±0.1 × 107 | 5.7±0.1 × 106 | 3.1±0.1 × 104 |
105 K | 1.8±0.1 × 106 | 4.1±0.1 × 106 | 6.7±0.1 × 105 | 2.5±0.1 × 104 |
