Table 1 Relationships between the signs of order parameters.

From: Coupled multiferroic domain switching in the canted conical spin spiral system Mn2GeO4

Condition before measurement

h [QA, QB]

P z

X1 (Γ1)

X3=Mz (Γ3)

X1X3 (CA or CB)

Q (QA or QB)

+E+B cool

[−, +]

+

+(−)

+

+(−)

QA(QB)

−B sweep

[+,−]

−

+(−)

−

−(+)

QB(QA)

+E−B cool

[−, +]

+

−(+)

−

+(−)

QA(QB)

+B sweep

[+,−]

−

−(+)

+

−(+)

QB(QA)

−E+B cool

[+, −]

−

+(−)

+

+(−)

QA(QB)

−B sweep

[−,+]

+

+(−)

−

−(+)

QB(QA)

−E−B cool

[+, −]

−

−(+)

−

+(−)

QA(QB)

+B sweep

[−,+]

+

−(+)

+

−(+)

QB(QA)

  1. The signs are determined by considering that an electric field E and a magnetic field B directly act on Pz and Mz, respectively, and by the U, V and W invariants in equations (1)–(3), . In the table, square brackets show the sign of h in each Q domain. The sign ‘+(−)’ denotes that either ‘+’ or ‘−’ domain is possible. However, within each experimental condition, the signs in and out of parentheses couple with those in and out of parentheses for other order parameters. Here, ‘+E+B cool’ means the field-cooled condition with positive E and B that are large enough to pole the system. ‘B-sweep’ denotes that B was swept to an opposite value once after the cooling procedure of the upper row. One-to-one correspondence between h and Pz is ascribed to the U term (equation (1)) and that between X1X3 and Q originates from the V term (equations (2)). In the column of X1X3, ‘+’ and ‘−’ refer to CA and CB commensurate domains, respectively. The relationships between the respective order parameters satisfy all experimental results (Table 2 and Supplementary Table 2).