Figure 2: Analysis of various metrics related to complex 2 derived from X-ray crystallography and 31P NMR spectroscopy. | Nature Communications

Figure 2: Analysis of various metrics related to complex 2 derived from X-ray crystallography and 31P NMR spectroscopy.

From: Unsupported boron–carbon σ-coordination to platinum as an isolable snapshot of σ-bond activation

Figure 2

aC–H distances in agostic complexes derived from neutron diffraction. bOnly metallacyclobutene derivatives with two definitive covalent metal-element bonds were considered, complexes with dative M←N(R)2C=C or M←O(R)C=C interactions were ignored. cExperimental covalent radii were derived from a published survey of the Cambridge Crystallographic Database54.

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