Figure 7: DOSY NMR showing uptake of 5 into micelles of 6.
From: Physical autocatalysis driven by a bond-forming thiol–ene reaction
(a) 2D DOSY spectrum shows rapid diffusion of 6. No 5 was directly observed in this experiment despite the solution being saturated before measurement. Experiment performed on a mixture of 6 (2 mM) and 5 (saturated; corresponding to Table 2 row D); (b) 2D DOSY spectrum shows the coincidence of diffusion coefficients for 5, 6 and TMS. Experiment performed on a mixture of 6 (50 mM), 2 (saturated) and TMS (saturated; corresponding to Table 2 row H). See also Supplementary Fig. 12.
