Figure 4: Encapsulation, characterization and stabilization of AMMVN within capsule 1.
From: Safe storage of radical initiators within a polyaromatic nanocapsule
(a) Schematic representation of the encapsulation of AMMVN within capsule 1 in aqueous solution. 1H NMR spectra (400 MHz, room temperature, D2O/CD3CN (9/1)) of 1⊃AMMVN in (b) the aromatic and (c) aliphatic regions. (d) Photostability (λirrad=360 nm, room temperature) and thermal stability (50 °C, dark) of AMMVN within/without 1. X-ray crystal structure of 1'⊃AMMVN: (e) stick (for 1') and cylindrical (for AMMVN) and (f) cylindrical (for 1') and space-filling (for AMMVN) representations (substituents and counterions are omitted for clarity).
