Figure 1: Hydrotrifluoromethylation of alkenes and alkynes. | Nature Communications

Figure 1: Hydrotrifluoromethylation of alkenes and alkynes.

From: Hydrotrifluoromethylation and iodotrifluoromethylation of alkenes and alkynes using an inorganic electride as a radical generator

Figure 1

(a) Previous reports of hydrotrifluoromethylation. (b) Hydrotrifluoromethylation using [Ca2N]+·e− as the electron donor. (c) Working model of the electride and the roles of EtOH. THF, tetrahydrofuran; TFE: 2,2,2-trifluoroethanol; DBU, 1,8-diazabicyclo[5.4.0]undec-7-ene; NMP, N-methyl-2-pyrrolidone; cat., catalyst; r.t., room temperature.

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