Figure 3: IR transmittance spectra and analysis.

(a) Representative IR transmittance spectra at high pressures, numbers show pressures in unit of GPa. The 0.23–0.28 eV region is obscured by diamond phonon absorptions from the DAC. (b) Pressure−energy−optical density (OD) contour, OD is defined as −log(T) while T is the transmittance. (c) Evolution of band gap under pressure. Circles are extrapolated indirect band gaps and the curve shows a parabolic fit of the band gap versus pressure. The band gap closure is observed at ∼40 GPa.