Metal clusters of different sizes may have particular electronic structures that affect their performance as catalysts.
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References
Kaden, W. E., Wu, T., Kunkel, W. A. & Anderson, S. L. Electronic structure controls reactivity of size-selected Pd clusters adsorbed on TiO2 surfaces. Science 326, 826–829 (2009).
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Reid, T. Size isn't all that matters. Nature Nanotech (2009). https://doi.org/10.1038/nnano.2009.374
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DOI: https://doi.org/10.1038/nnano.2009.374