Abstract
The chemical composition distribution (CCD) of a high-conversion sample of styrene–methyl acrylate statistical copolymer was determined by thin-layer chromatography (TLC). The CCD was compared with the CCD determined by cross fractionation and also with that calculated theoretically in our previous work. The agreement among the three CCD’s was sutisfactory.
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References
V. A. Agasandyan, L. G. Kudryavtseva, A. D. Litomanovich, and V. Ya. Shtern, Vysokomol. Soedin., Ser. A, 9, 2634 (1967).
S. Teramachi and Y. Kato, J. Macromol. Sci., Chem., 4, 1785 (1970).
S. Teramachi and Y. Kato, Macromolecuels, 4, 54 (1971).
S. Teramachi and T. Fukao, Polym. J., 6, 532 (1974).
J. Stejskal and P. Kratochvil, Macromolecules, 11, 1097 (1978).
S. Teramachi, A. Hasegawa, S. Hasegawa, and T. Ishibe, Polym. J., 13, 319 (1981).
H. Inagaki, H. Matsuda, and F. Kamiyama, Macromolecules, 1, 520 (1968).
Wälchli, T. Miyamoto, and H. Inagaki, Bull. Inst. Chem. Res., Kyoto Univ., 56, 80 (1978).
N. Tagata and T. Homma, Nippon Kagaku Kaishi, 1330 (1972).
T. Tanaka, M. Omoto, N. Donkai, and H. Inagaki, J. Macromol. Sci., Phys., B17, 211 (1980).
S. Teramachi, A. Hasegawa, Y. Shima, M. Akatsuka, and M. Nakajima, Macromolecules, 12, 992 (1979).
S. Teramachi, A. Hasegawa, M. Akatsuka, A. Yamashita, and N. Takemoto, Macromolecules, 11, 1206 (1978).
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Teramachi, S., Hasegawa, A. & Yoshida, S. Comparison of Cross Fractionation and TLC Methods in the Determination of the Compositional Distribution of a Statistical Copolymer. Polym J 14, 161–164 (1982). https://doi.org/10.1295/polymj.14.161
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DOI: https://doi.org/10.1295/polymj.14.161