Abstract
Organometallic polymers containing tin and transition metals have been synthesized by polycondensation between dimethyldi(4-ethynylphenyl)tin and transition metal halides using cuprous iodide as a catalyst in diethylamine. The polymers, in which tin and transition metals are regularly linked by a conjugated system through M-C bonds, are characterized by spectral analyses.
Similar content being viewed by others
Log in or create a free account to read this content
Gain free access to this article, as well as selected content from this journal and more on nature.com
or
References
See, for example, J. E. Sheats, C. U. Pittman, Jr., and C. E. Carraher, Jr., Chem. Br., 20, 709 (1984).
C. E. Carraher, Jr., “Interfacial Synthesis,” Vol. II, F. Millich and C. E. Carraher, Jr., Ed., Marcel Dekker, New York, N. Y., 1977, p 366.
W. P. Neumann and B. Schneider, Justus Liebigs Ann. Chem., 707, 20 (1967).
N. Hagihara, K. Sonogashira, and S. Takahashi, Adv. Polym. Sci., 41, 149 (1981).
S. Takahashi, M. Kariya, T. Yatake, K. Sonogashira, and N. Hagihara, Macromolecules, 11, 1063 (1978).
S. Takahashi, Y. Kuroyama, K. Sonogashira, and N. Hagihara, Synthesis, 627 (1980).
S. Takahashi, E. Murata, K. Sonogashira, and N. Hagihara, J. Polym. Sci., Polym. Chem. Ed., 18, 661 (1980).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Tahara, T., Seto, K. & Takahashi, S. Synthesis and Characterization of Polymers Containing Tin and Transition Metals in the Main Chain. Polym J 19, 301–304 (1987). https://doi.org/10.1295/polymj.19.301
Issue date:
DOI: https://doi.org/10.1295/polymj.19.301
Keywords
This article is cited by
-
Novel polycondensation catalyzed by a palladium complex
Polymer Bulletin (1989)