Abstract
Four new types of poly(N-substituted maleimide) macromonomers (RMI, R=N-substituent, phenyl and cyclohexyl) were synthesized from methacryloyloxyethyl isocyanate (MOI) and oligomaleimides. The obtained macromonomers were polymerized in tetrahydrofuran (THF) to afford the corresponding polymacromonomers with degradation temperature of 266-272°C in high yields. The radical polymerizations of the macromonomers with styrene (ST) or methyl methacrylate (MMA) were performed in THF at 60°C to give the corresponding copolymers. The obtained copolymers exhibited higher glass transition temperatures than those of poly(ST) and poly(MMA).
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Oishi, T., Lee, YK., Nakagawa, A. et al. Synthesis and Polymerization of Poly(N-substituted maleimide) Macromonomers. Polym J 33, 81–88 (2001). https://doi.org/10.1295/polymj.33.81
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DOI: https://doi.org/10.1295/polymj.33.81
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