Abstract
Injected foams obtained from blends with different compositions of isotactic polypropylene, iPP, and two different low density polyethylenes, LDPE, were analyzed by X-Ray diffraction, differential scanning calorimetry, and dynamic mechanical thermal analysis. Most of the results on the blends can be simulated as a weighed addition of the two pure components, indicating practical immiscibility. Some features about the crystallization of the iPP component pointed out inhibition and, consequently, a delay in the development of monoclinic crystalline entities.
Similar content being viewed by others
Login or create a free account to read this content
Gain free access to this article, as well as selected content from this journal and more on nature.com
or
References
B. Z. Jang, D. R. Uhlmann, and J. B. Vander Sande, J. Appl. Polym. Sci., 29, 4377 (1984).
Y. Kim, W. J. Cho, and C. S. Ha, Polym. Eng. Sci., 35, 1592 (1995).
C. L. Wang, S. J. Wang, and Z. N. Qi, J. Polym. Sci., Part B: Polym. Phys., 34, 193 (1996)
A. Van der Wall, R. Mighof, and R. J. Gaymans, Polymer, 40, 6087 (1999).
S. H. Jafari and A. K. Gupta, J. Appl. Polym. Sci., 78, 962 (2000).
N. Touleshkov, S. Djoumaliisky, and G. Kotzev, Polym. Degrad. Stabil., 24, 327 (1989).
G. Kotzev and N. Touleshkov, J. Mater. Sci. Technol., 4, 33 (1996).
S. Djoumaliisky and N. Touleshkov, J. Mater. Sci. Technol., 4, 32 (1996).
S. Djoumaliisky, N. Touleshkov, and G. Kotzev, Polym.-Plast. Technol. Eng., 36, 257 (1997).
S. Djoumaliisky, D. Christova, N. Touleshkov, and E. Nedkov, J. Macramol. Sci., Pure Appl. Chem., A35, 1147 (1998).
G. Kotzev, N. Touleshkov, D. Christova, and E. Nedkov, J. Macramol. Sci., Pure Appl. Chem., A35, 1127 (1998).
G. Kotzev, N. Touleshkov, D. Christova, and E. Nedkov, J. Cell. Plast., 36, 29 (2000).
D. Christova, N. Touleshkov, S. Djoumaliisky, G. Kotzev, and E. Nedkov, Proc. of 9th International Conference on MECHANICS AND TECHNOLOGY OF COMPOSITE MATERIALS, 11–14 (2000).
B. Wunderlich, Macromolecular Physics, Academic Press, New York, N.Y., 1980, 3, p. 42.
J. R. Isasi, L. Mandelkern, M. J. Galante, and R. G. Alamo, J. Polym. Sci., Part B: Polym. Phys., 37, 323 (1999).
N. G. McCrum, B. E. Read, and G. Williams, Anelastic and Dielectric Effects in Polymeric Solids, Chapt. 10, Dover Publications, New York, N.Y., 1991. p. 353.
O. Prieto, J. M. Pereña, R. Benavente, M. L. Cerrada, and E. Pérez, Macromol. Chem. Phys., 203, 1844 (2002).
A. Alizadeh, L. Richardson, J. Xu, S. McCartney, H. Marand, Y. W. Cheung, and S. Chum, Macromolecules, 32, 6221 (1999).
J. Li, R. A. Shanks, R. H. Olley, and G. R. Greenway, Polymer, 42, 7685 (2001).
I. M. Ward, Mechanical Properties of Solids Polymers, 2nd. ed, John Wiley and Sons Inc., Chischester UK, 1985.
L. E Nielsen and R. F. Landel, Mechanical Properties of Polymers and Composites, 2nd ed, Marcel Dekker, New York, N.Y., 1994.
C. Jourdan, J. Y. Cavaille, and J. Perez, J. Polym. Sci., Part B: Polym. Phys., 27, 2361 (1989).
F. Schatzki, J. Polym. Sci., 57, 496 (1962).
R. G. C. Arridge, Rev. Deform. Behav. Mater., 3, 249 (1981).
R. H. Boyd, Polymer, 26, 1123 (1985).
R. F. Boyer, Rubb. Chem. Technol., 36, 1303 (1963).
R. H. Boyd and R. S. Breitling, Macromolecules, 7, 855 (1974).
R. H. Boyd, J. Polym. Sci., Part B: Polym. Phys., 13, 2345 (1975).
N. J. Heaton, R. Benavente, E. Pérez, A. Bello, and J. M. Pereña, Polymer, 37, 3791 (1996).
R. H. Boyd, R. H. Gee, J. Han, and Y. Jin, J. Chem. Phys., 101, 788 (1994).
Y. Jin and R. H. Boyd, J. Chem. Phys., 108, 9912 (1998).
R. Popli and L. Mandelkern, Polymer Bull., 9, 260 (1983).
R. Popli, M. Glotin, L. Mandelkern, and R. S. Benson, J. Polym. Sci., Part B: Polym. Phys., 22, 407 (1984).
R. H. Boyd, Macromolecules, 17, 903 (1984).
J. Han, R. H. Gee, and R. H. Boyd, Macromolecules, 27, 7781 (1994).
O. Prieto, J. M. Pereña, R. Benavente, E. Pérez, and M. L. Cerrada, J. Polym. Sci., Part B: Polym. Phys., 41, 1878 (2003).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Benavente, R., Pereña, J., Pérez, E. et al. Structural Characterization and Relaxation Processes of the Inner Crystalline Core in Foams Based on Polyethylene/Polypropylene Blends. Polym J 35, 920–927 (2003). https://doi.org/10.1295/polymj.35.920
Issue date:
DOI: https://doi.org/10.1295/polymj.35.920