Abstract
The copolymers of glycidyl methacrylate/vinylidene chloride (G/C) were synthesized and the quantitative 13C{1H} NMR spectrum was used to determine the copolymer composition. The comonomer reactivity ratios as determined by Kelen–Tudos (KT) and non-linear least squares error in variable method (EVM) are rG=2.55 ± 0.56, rc=0.26 ± 0.06 and rG=2.7, rc=0.27, respectively. The Distortionless Enhancement by Polarization Transfer (DEPT), heteronuclear single quantum coherence (HSQC) and Total Correlation Spectroscopy (TOCSY) were used for the complete spectral assignments of 13C{1H} and 1H NMR spectra.
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Brar, A., Yadav, A. Glycidyl Methacrylate and Vinylidene Chloride Copolymers. Nuclear Magnetic Resonance Characterisation. Polym J 35, 37–43 (2003). https://doi.org/10.1295/polymj.35.37
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DOI: https://doi.org/10.1295/polymj.35.37
