Abstract
To produce high performance optical adhesives, adhesives were prepared by mixing triethoxy vinylsilane (TVSi) as a silane coupling agent into basic compositions consisting of 15 wt% 2-hydroxyethyl methacrylate (HEMA), oligo-siloxanyl dimethacrylate (SiMA) and acrylicacid tricyclo [5,2,1,02,6] decane (TCDA). When the composition includes TCDA from 43 to 69 wt%, copolymers polymerized from the composition exhibit high adhesion strength to glass, good optical transparency and excellent water-resistance. The high quality of the adhesives comes from microscopically homogeneous structures of the copolymers in which all components are mixed randomly.
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References
T. Maruno and K. Nakamura, J. Appl. Polym. Sci., 142, 2141 (1991).
T. Maruno, K. Nakamura, and N. Murata, Macromolecules, 29, 2006 (1996).
T. Sawamoto and S. Ikeda, presented at 7th SPSJ International Polymer Conference, Yokahama, Japan, Oct. 26–29, 1999.
T. Sawamoto and S. Ikeda, Kobunshi Ronbunshu, 57, 425 (2000).
T. Fukushima, J. L. Ferracane, T. Horibe, and T. Okabe, Dent. Mater. J., 7, 1 (1988).
H. Ohno, Y. Araki, K. Endo, Y. Yamabe, and I. Kawashima, Dent. Mater. J., 15, 183 (1996).
R. A. Jurf and J. R. Vinson, J. Mater. Sci., 20, 2979 (1985).
A. Dufence and C. Lacabanne, Polymer, 36, 4417 (1995).
H. Ishida and J. Koenig, J. Polym. Sci., Polym. Phys. Ed., 18, 233 (1980).
S. Kurata and N. Yamazaki, Dent. Mater. J., 12, 127 (1993).
C. H. Chiang and J. L. Koenig, J. Polym. Sci., Polym. Phys. Ed., 20, 2135 (1982).
C. H. Chiang, H. Ishida, and J. L. Koenig, J. Colloid Interface Sci., 74, 396 (1980).
G. G. Cameron and M. S. Chipsholm, Polymer, 27, 1420 (1986).
K. Pathmanathan and G. P. Johari, J. Polym. Sci., Polym. Phys. Ed., 28, 675 (1990).
Hayakawa, “Busshitsu To Hikari,” Asakura Shoten, Tokyo, 1980, p 44.
Masaki, “Kougakugijutsu Handbook,” Asakura Shoten, Tokyo, 1975, p 1113.
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Sawamoto, T., Ikeda, S. Water Resistance and Optical Properties of Optical Adhesives Containing Strong Hydrophobic Components. Polym J 36, 310–315 (2004). https://doi.org/10.1295/polymj.36.310
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DOI: https://doi.org/10.1295/polymj.36.310