Abstract
Asymmetric alternating copolymerization of α-olefins (mono-substituted ethenes) with CO provides chiral polyketones in their optically pure forms. Conformation of the polyketones is elucidated in a solution and in a solid state. Studies on the chemical transformation of the functional group, the ketone moiety, are also described.
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Nozaki, K. Optically Active Polyketones: Synthesis, Structure, and Reactions. Polym J 37, 871–876 (2005). https://doi.org/10.1295/polymj.37.871
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DOI: https://doi.org/10.1295/polymj.37.871
