Table 1 Photopolymerization of St with 1a–g as initiatorsa

From: 1-(Arylmethyloxy)anthracenes: how substituents affect their photoreactivity and ability to initiate radical and cationic polymerizations

Initiator

Time (h)

Temperature (°C)

Yield (%)

Mn × 10−4

M w /M n

1a

8

RT

15.7

2.0

3.2

 

8

60

31.5

3.2

2.8

 

12

60

44.9

5.6

2.9

1b

8

RT

19.7

2.1

2.4

 

8

60

36.7

3.1

2.9

 

12

60

64.2

5.7

3.1

1c

8

RT

24.3

2.1

2.4

 

8

60

57.8

3.2

3.0

 

12

60

76.5

5.9

3.2

1d

8

RT

13.8

3.4

2.4

 

8

60

21.1

4.2

2.9

 

12

60

42.8

7.1

3.0

1e

8

RT

5.8

3.2

2.7

 

8

60

13.4

3.4

2.6

 

12

60

24.0

5.7

3.2

1f

8

RT

7.8

2.9

2.7

 

8

60

19.0

4.8

2.7

 

12

60

34.9

6.8

2.8

1g

8

RT

5.2

6.8

2.3

 

8

60

8.9

10.3

2.7

 

12

60

15.6

11.1

2.6

  1. Abbreviation: RT, room temperature.
  2. [Initiator]/[St]=0.2 mol%. The initiator was irradiated with λ>340 nm.
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