Table 3 General information about oxylipins monitored.
Precursor ion [M-H]- | Specific fragment [M-H]- | Oxylipin | RT (min) | R2 | LOD (pg) | LOQ (pg) | CE (eV) |
|---|---|---|---|---|---|---|---|
295.2 | 171.1027 | 9-HODE | 6.35 | 0.999 | 1.0 | 1.0 | 25 |
295.2 | 195.1391 | 13-HODE | 6.29 | 1.000 | 1.0 | 1.0 | 25 |
313.2 | 183.1391 | 12(13)-DiHOME | 5.27 | 1.000 | 0.5 | 0.5 | 23 |
313.2 | 201.1132 | 9(10)-DiHOME | 5.43 | 1.000 | 0.5 | 0.5 | 23 |
315.2 | 271.2067 | 15-deoxy-Δ12,14-PGJ2 | 5.92 | 0.999 | 0.5 | 0.5 | 13 |
319.2 | 115.0401 | 5-HETE | 6.81 | 0.999 | 0.5 | 3.9 | 19 |
319.2 | 167.1078 | 11-HETE | 6.52 | 1.000 | 0.5 | 0.5 | 19 |
319.2 | 179.1078 | 12-HETE | 6.60 | 1.000 | 1.0 | 1.0 | 19 |
319.2 | 113.0972 | 15-HETE | 6.38 | 1.000 | 2.0 | 7.8 | 19 |
321.2 | 181.1234 | 12-HETrE | 6.79 | 1.000 | 0.5 | 0.5 | 18 |
321.2 | 221.1547 | 15-HETrE | 6.65 | 1.000 | 0.5 | 0.5 | 18 |
333.2 | 189.1285 | PGA2 | 4.36 | 1.000 | 4.9 | 4.9 | 17 |
333.2 | 233.1183 | PGJ2 | 4.41 | 0.998 | 2.4 | 4.9 | 17 |
333.2 | 235.1340 | PGB2 | 4.44 | 0.999 | 4.9 | 4.9 | 17 |
333.2 | 271.2067 | 15-deoxy-Δ12,14-PGD2 | 5.12 | 0.999 | 4.9 | 4.9 | 17 |
343.2 | 234.1261 | 14-HDoHE | 6.47 | 0.999 | 11.7 | 11.7 | 18 |
343.2 | 245.1547 | 17-HDoHE | 6.37 | 0.999 | 11.7 | 11.7 | 18 |
349.2 | 235.0976 | 15-keto-PGE2 | 3.56 | 1.000 | 2.4 | 2.4 | 15 |
349.2 | 269.1911 | PGE3 | 2.83 | 0.999 | 1.5 | 1.5 | 15 |
349.2 | 269.1911 | PGD3 | 2.99 | 0.999 | 1.5 | 1.5 | 15 |
351.2 | 271.2067 | PGE2 | 3.34 | 1.000 | 2.4 | 2.4 | 17 |
351.2 | 271.2067 | PGD2 | 3.52 | 0.996 | 4.9 | 4.9 | 17 |
351.2 | 115.0401 | LXA4 | 3.90 | 1.000 | 1.5 | 1.5 | 17 |
353.2 | 235.1340 | PGD1 | 3.51 | 0.997 | 2.4 | 2.4 | 21 |
353.2 | 309.2071 | PGF2α | 3.19 | 0.999 | 4.9 | 4.9 | 21 |
353.2 | 115.0401 | 8,12-iso-iPF2α -VI | 3.87 | 1.000 | 0.7 | 1.5 | 21 |
355.2 | 311.2228 | 13,14-dihydro-PGF2α | 3.60 | 0.999 | 4.9 | 4.9 | 23 |
355.2 | 311.2228 | PGF1α | 3.19 | 0.996 | 4.9 | 4.9 | 23 |
359.2 | 153.0921 | Protectin-D1 | 4.83 | 1.000 | 1.5 | 1.5 | 20 |
359.2 | 250.1211 | Maresin-1 | 4.96 | 1.000 | 5.9 | 11.7 | 20 |
367.2 | 143.0714 | 6-keto-PGE1 | 2.20 | 1.000 | 4.9 | 4.9 | 21 |
369.2 | 245.1911 | 6-keto-PGF1α | 1.94 | 1.000 | 4.9 | 9.8 | 26 |
369.2 | 267.1602 | 6,15-diketo-13,14-dihydro-PGF1α | 2.76 | 1.000 | 11.7 | 46.9 | 26 |
375.2 | 215.1441 | Resolvin-D1 | 3.85 | 1.000 | 1.5 | 11.7 | 20 |
