Table 2 Barocaloric performance of H2O-1.33 wt% GdCl3 compared with representative organic and inorganic BCE materials.
From: Colossal barocaloric effect in GdCl3-doped H2O for sustainable cooling
Compound | ΔSiso (J·kg-1·K-1) | ΔSr (J·kg-1·K-1) | Psat (kbar) | ΔSr/Psat (J·kg-1·K-1·bar-1) | RCrev (J·kg-1) | RCrev/P (J·kg-1·GPa-1) | Ref. | |
|---|---|---|---|---|---|---|---|---|
organic | C16H34 | 762 | 762 | 0.6 | 1.27 | 5900 (0.1 GPa) | 59000 | |
C18H38 | 711 | 711 | 0.4 | 1.7775 | 7800 (0.1 GPa) | 78000 | ||
Para-carborane | 106.2 | 97.3 | 0.4 | 0.24325 | 1100 (0.06 GPa) | 18333 | ||
NPG | 384 | 384 | 2.5 | 0.1536 | 6700 (0.57 GPa) | 11754 | ||
PG | 510 | 479 | 0.4 | 1.1975 | 4500 (0.24 GPa) | 18750 | ||
NPA | 500 | 197 | 1.8 | 0.10944 | 4500 (0.33 GPa) | 13636 | ||
TRIS | 600 | 600 | 50 | 0.01198 | 0 (0.25 GPa) | 0 | ||
AMP | 690 | 632 | 6 | 0.10533 | 0 (0.25 GPa) | 0 | ||
PEG10000/PET15000 | 543 | 426 | 3 | 0.142 | 3000 (0.4 GPa) | 7500 | ||
(C9H19NH2)2MnCl4 | 212 | 212 | 0.8 | 0.265 | 1060 (0.1 GPa) | 10600 | ||
(C10H21NH2)2MnCl4 | 230 | 230 | 0.8 | 0.2875 | 1150 (0.1 GPa) | 11500 | ||
Inorganic | Fe[HB(tz)3]2 | 99 | 90 | 0.15 | 0.6 | 180 (0.015 GPa) | 12000 | |
Fe(L)(NCS)2 | 110 | 110 | 1 | 0.11 | 2500 (0.1 GPa) | 25000 | ||
Fe3(bntrz)6(tcnset)6 | 120 | 100 | 0.6 | 0.16667 | 7200 (0.26 GPa) | 27692 | ||
[TPrA][Mn(dca)3] | 38 | 32 | 0.3 | 0.10667 | 66 (0.007 GPa) | 9428 | ||
C7H14NReO4 | 90 | 80 | 2.3 | 0.03478 | 2700 (0.28 GPa) | 9643 | ||
[Cp2Fe][PF6] | 55 | 55 | 0.9 | 0.06111 | 1050 (0.1 GPa) | 10500 | ||
MnCoGeB0.03 | 35 | 30 | 1.7 | 0.01765 | 400 (0.48 GPa) | 833 | ||
AgI | 60 | 60 | 2.2 | 0.02727 | 450 (0.25 GPa) | 1800 | ||
(NH4)2SO4 | 55 | 55 | 2 | 0.0275 | 460 (0.25 GPa) | 1840 | ||
C60 | 50 | 50 | 5.9 | 0.00847 | 4000 (0.59 GPa) | 6780 | ||
NH4I | 90 | 90 | 0.7 | 0.12857 | 1400 (0.08 GPa) | 17500 | ||
H2O-1.33 wt%GdCl3 | 1050 | 1018 | 1.6 | 0.64375 | 9700 (0.19 GPa) | 51052 | This worka |
