Fig. 2 | Polymer Journal

Fig. 2

From: Radical polymerization of alkenyl boronates and C–B bond transformation: polymer synthesis through side-chain replacement for overcoming synthetic limitations

Fig. 2

a Comparison of size exclusion chromatography (SEC) traces in the radical polymerization of IPBpin, 2-methyl-1-nonene, and isopropenyl acetate ([Alkenyl compound]/[AIBN] = 4000 mM/40 mM in toluene at 60 °C). b DFT-based calculation of the total energy change in degenerative chain transfer dependent on the monomer structure [(U)B3LYP/6-31 G(d)]. c Side-chain replacement of poly(IPBpin) for the synthesis of poly(α-methyl vinyl alcohol) and poly(α-methyl vinyl amine) (Reproduced with permission from Ref. [34]. Copyright 2019 Wiley-VCH)

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