Table 1 MS and MS² data of laetiporic acid pairs A₁/A₂–D₁/D₂

From: The Laetiporus polyketide synthase LpaA produces a series of antifungal polyenes

Compound	t_R (min)	Formula	Neutral mass [M]	Found parental ion [M + H]⁺	MS² specific ions
Compound	t_R (min)	Formula	Neutral mass [M]	Found parental ion [M + H]⁺	Ion mass	Formula	Origin
LA-A₁/A₂	4.7/4.9	C₂₇H₃₂O₄	420.2301	421.2374/421.2371	403.227	C₂₇H₃₁O₃	[M-H₂O + H]⁺
					385.216	C₂₇H₂₉O₂	[M-2 H₂O + H]⁺
					359.236	C₂₆H₃₁O	[M-H₂O-CO₂ + H]⁺
					343.190	C₂₁H₂₇O₄	[M-C₆H₆ + H]⁺
					245.132	C₁₉H₁₇	[M-C₈H₈-H₈O₄ + H]⁺
					219.117	C₁₇H₁₅	[M-C₁₀H₁₀-H₈O₄ + H]⁺
					193.101	C₁₅H₁₃	[M-C₁₂H₁₂-H₈O₄ + H]⁺
					131.086	C₁₀H₁₁	[C₁₀H₁₀ + H]⁺
					109.065	C₇H₁₀O	[C₇H₉O + H]⁺
					105.070	C₈H₉	[C₈H₈ + H]⁺
					79.054	C₆H₇	[C₆H₆ + H]⁺
LA-B₁/B₂	5.1/5.3	C₂₉H₃₄O₄	446.2457	447.2524/447.2524	429.242	C₂₉H₃₃O₃	[M-H₂O + H]⁺
					411.231	C₂₉H₃₁O₂	[M-2 H₂O + H]⁺
					369.204	C₂₃H₂₉O₄	[M-C₆H₆ + H]⁺
					351.195	C₂₃H₂₇O₃	[M-C₆H₆-H₂O + H]⁺
					312.172	C₂₀H₂₄O₃	[M-C₉H₉-H₂O + H]⁺
					271.148	C₂₁H₁₉	[M-C₈H₈-H₈O₄ + H]⁺
					245.132	C₁₉H₁₇	[M-C₁₀H₁₀-H₈O₄ + H]⁺
					219.117	C₁₇H₁₅	[M-C₁₂H₁₂-H₈O₄ + H]⁺
					193.101	C₁₅H₁₃	[M-C₁₄H₁₄-H₈O₄ + H]⁺
					131.086	C₁₀H₁₁	[C₁₀H₁₀ + H]⁺
					109.065	C₇H₁₀O	[C₇H₉O + H]⁺
					105.070	C₈H₉	[C₈H₈ + H]⁺
					79.054	C₆H₇	[C₆H₆ + H]⁺
LA-C₁/C₂	5.7/5.9	C₃₁H₃₆O₄	472.2614	473.2686/473.2687	455.258	C₃₁H₃₅O₃	[M-H₂O + H]⁺
					395.219	C₂₅H₃₁O₄	[M-C₆H₆ + H]⁺
					338.188	C₂₂H₂₆O₃	[M-C₉H₉-H₂O + H]⁺
					245.132	C₁₉H₁₇	[M-C₁₂H₁₂-H₈O₄ + H]⁺
					219.117	C₁₇H₁₅	[M-C₁₄H₁₄-H₈O₄ + H]⁺
					193.101	C₁₅H₁₃	[M-C₁₆H₁₆ -H₈O₄ + H]⁺
					131.086	C₁₀H₁₁	[C₁₀H₁₀ + H]⁺
					109.065	C₇H₁₀O	[C₇H₉O + H]⁺
					105.070	C₈H₉	[C₈H₈ + H]⁺
					79.054	C₆H₇	[C₆H₆ + H]⁺
LA-D₁	6.2	C₃₃H₃₈O₄	498.2770	499.2844	481.2742	C₃₃H₃₇O₃	[M-H₂O + H]⁺
					421.2373	C₂₇H₃₃O₄	[M-C₆H₆ + H]⁺
					364.203	C₂₄H₂₈O₃	[M-C₉H₉-H₂O + H]⁺
					297.163	C₂₃H₂₁	[M-C₁₀H₁₀-H₈O₄ + H]⁺
					219.117	C₁₇H₁₅	[M-C₁₆H₁₆-H₈O₄ + H]⁺
					193.101	C₁₅H₁₃	[M-C₁₈H₁₈-H₈O₄ + H]⁺
					131.086	C₁₀H₁₁	[C₁₀H₁₀ + H]⁺
					109.065	C₇H₁₀O	[C₇H₉O + H]⁺
					105.070	C₈H₉	[C₈H₈ + H]⁺
					79.054	C₆H₇	[C₆H₆ + H]⁺
LA-D₂	6.4	C₃₃H₃₈O₄	498.2770	499.2832	not determined.

Back to article page

Table 1 MS and MS² data of laetiporic acid pairs A₁/A₂–D₁/D₂

Search

Quick links