Fig. 7
From: From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond
Molecular and geometry optimized structures of 5 and 5′. (a) Molecular structure of 5. H-atoms were omitted for clarity, displacement ellipsoids are drawn at the 50% probability level. b Geometry optimized structure of 5′, with the HOMO plotted. Selected bond lengths and angles: 5, Ga–Sb 2.5528(2), 2.4629(2) Å, Ga–Sb–Ga 113.184(7)°; 5′, Ga–Sb 2.639, 2.535 Å, Ga–Sb–Ga 118.94°
