Fig. 3

Characterization of mixed-metal self-assembled complexes. 1H NMR spectra (400 MHz, CD3CN, 298 K) of a [La4(L1)4](ClO4)12, b [Ce4(L1)4](CF3SO3)12, and c LaIII/CeIII mixed-metal self-assembled complexes. ESI-TOF-MS spectrum d of the LaIII/CeIII mixed-metal self-assembled complexes (ClO4− salts) with insets showing the observed (Obs.) and fitted isotope patterns of the 5 + peak from simulations (Sim.) of the component signals