Table 1 Magnetic and thermodynamic properties of Sr2Cu(Te0.5W0.5)O6, Sr2CuTeO6 and Sr2CuWO6

From: Spin-liquid-like state in a spin-1/2 square-lattice antiferromagnet perovskite induced by d10d0 cation mixing

 

Sr2Cu(Te0.5W0.5)O6

Sr2CuTeO6

Sr2CuWO6

Tmax (K)

52

74

86

χmax (10-3emu/mol)

2.55

2.24

1.55

μeffB)

1.87

1.87

1.90

Θcw (K)

−71

−80

−165

TN (K)

<0.019

2924

2417

k

[½ ½ 0]24

[0 ½ ½]23

f = |Θcw|/TN

>3700

≈3

≈7

γ (mJ/molK2)

54.2

2.2

0.7

βD (K)

395

381

361